• 文献标题:   Boron-Doped Graphene Oxide-Supported Nickel Nitride Nanoparticles for Electrocatalytic Oxygen Evolution in Alkaline Electrolytes
  • 文献类型:   Article
  • 作  者:   LI B, SONG FH, QIAN YQ, SHAW J, RAO Y
  • 作者关键词:   hydrogen energy economy, water oxidation, noblemetalbased electrocatalyst, interface catalyst, pn junction
  • 出版物名称:   ACS APPLIED NANO MATERIALS
  • ISSN:   2574-0970
  • 通讯作者地址:   Utah State Univ
  • 被引频次:   0
  • DOI:   10.1021/acsanm.0c01963
  • 出版年:   2020

▎ 摘  要

The development of efficient oxygen evolution reaction (OER) electrocatalysts is crucial for hydrogen energy economy. While noble-metal-based electrocatalysts show excellent performance in the OER, the scarcity and high cost of noble metals limit their widespread applications. Herein, we report an efficient and stable noble-metal-free catalyst for the OER. We synthesized a high-performance interface catalyst, boron-doped graphene (BGO) nanosheet-supported nickel nitride (Ni3N) nanoparticles BGO/Ni3N, for the OER in alkaline electrolytes. This metal-free catalyst BGO/Ni3N exhibits high electrocatalytic OER activity and kinetics with a low overpotential of 290 mV at a current density of 10 mA.cm(-2) and a small Tafel slope of 77.9 mV.dec(-1) in a 1 M KOH solution. Moreover, the catalysts show excellent OER stability and durability. The strong electronic coupling between p-type BGO and n-type Ni3N as well as increased electrical conductivity of BGO might be responsible for the good conductivity and fast charge transfer in the OER.