• 文献标题:   Aqueous synthesis of glutathione-capped CuInS2/ZnS quantum dots-graphene oxide nanocomposite as fluorescence "switch OFF" for explosive detection
  • 文献类型:   Article
  • 作  者:   MALULEKE R, SAKHO EM, OLUWAFEMI OS
  • 作者关键词:   nanocomposite, fluorescence, quenching, detection, explosive, trinitrophenol
  • 出版物名称:   MATERIALS LETTERS
  • ISSN:   0167-577X EI 1873-4979
  • 通讯作者地址:   Univ Johannesburg
  • 被引频次:   0
  • DOI:   10.1016/j.matlet.2020.127669
  • 出版年:   2020

▎ 摘  要

This work reports a simple and fast aqueous preparation of CuInS2/ZnS-graphene oxide (CIS/ZnS-GO) nanocomposite as a fluorescence "switch OFF" probe for the fluorescence detection of 2, 4, 6-trinitrophenol (TNP.) - a raw material for various explosive devices. The as-synthesized nanocomposites was characterised using Ultraviolet-visible (UV-Vis) spectroscopy, photoluminescence (PL) spectroscopy, high resolution transmission electron microscopy (HR-TEM), Fourier-transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD) and Raman scattering. The PL studies revealed that the adsorption of TNP onto GO via pi-pi stacking enhanced the charges transfer from CuInS2/ZnS-GO to the analyte. The limit of detection (LOD) for the analyte is 57 mu M. (C) 2020 Elsevier B.V. All rights reserved.