• 文献标题:   Removal of Hg(II) from aqueous solution by resin loaded magnetic beta-cyclodextrin bead and graphene oxide sheet: Synthesis, adsorption mechanism and separation properties
  • 文献类型:   Article
  • 作  者:   CUI LM, WANG YG, GAO L, HU LH, WEI Q, DU B
  • 作者关键词:   go, magnetic betacyclodextrin, hg ii, kinetic, thermodynamic, isotherm
  • 出版物名称:   JOURNAL OF COLLOID INTERFACE SCIENCE
  • ISSN:   0021-9797 EI 1095-7103
  • 通讯作者地址:   Univ Jinan
  • 被引频次:   50
  • DOI:   10.1016/j.jcis.2015.06.007
  • 出版年:   2015

▎ 摘  要

Resin loaded magnetic beta-cyclodextrin bead and graphene oxide sheet (MCD-GO-R) was synthesized successfully and found to be an excellent adsorbent for Hg(II) removal. The as-prepared adsorbent was characterized by SEM, FTIR, BET, magnetization curve and zeta potential analysis respectively. Good magnetic performance made MCD-GO-R simply recover from aqueous solution at low magnetic field within 30 s. And also, the rich functional groups and outstanding dispersity play an important role in the adsorption process. The maximum adsorption capacity was 88.43 mg g(-1) at 323 K and pH 7.1. The as-prepared adsorbent could perform well in a wide pH range from 4.0 to 10.0. Static adsorption experimental data showed good correlation with pseudo-second-order model and Freundlich isotherm models. It was found that the contaminant adsorption was accomplished mainly via chelation or ion exchange and come to equilibrium in only 30 min. All experimental results, especially the excellent reproducibility and resistance to ion interference, suggest that MCD-GO-R has promising applications in water treatment. (C) 2015 Elsevier Inc. All rights reserved.