• 文献标题:   Ultrafine palladium nanoparticles anchoring graphene oxide-ionic liquid grafted chitosan self-assembled materials: The novel organic-inorganic hybrid catalysts for hydrogen generation in hydrolysis of ammonia borane
  • 文献类型:   Article
  • 作  者:   JIA H, CHEN X, LIU CY, LIU XJ, ZHENG XC, GUAN XX, LIU P
  • 作者关键词:   graphene oxideionic liquid chitosan, selfassembly, palladium nanoparticle, organicinorganic hybrid catalyst, ammonia borane, hydrogen generation
  • 出版物名称:   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • ISSN:   0360-3199 EI 1879-3487
  • 通讯作者地址:   Zhengzhou Univ
  • 被引频次:   10
  • DOI:   10.1016/j.ijhydene.2018.04.156
  • 出版年:   2018

▎ 摘  要

The novel graphene oxide-ionic liquid grafted chitosan composites (denoted as GO-ILCS) are firstly prepared via a self-assembly process. Then, they are used to anchor ultrafine palladium nanoparticles by the in-situ reduction of palladium chloride with sodium borohydride. The resultant Pd(0)/GO-ILCS organic-inorganic hybrid catalysts are characterized by various techniques and used to catalyze the hydrolytic dehydrogenation of ammonia borane (NH3BH3, AB) under ambient conditions. The results reveal that the palladium nanoparticles are highly dispersed on GO-ILCS and the Pd(0)/GO-ILCS catalysts exhibit high catalytic activity and excellent reusability in the reaction. The turnover frequency (TOF) is as high as 25.6 mol(H2), center dot mol(Pd)(-1)center dot min(-1) and the catalytic activity does not decrease obviously after six runs. The orders of palladium and AB concentrations are 1.00 and 0.33 in the catalytic reaction, respectively. Notably, the activation energy of the reaction (Ea = 38 kJ mol(-1)) over the resultant catalysts is obviously lower than most of the palladium-based catalysts reported previously. It is expected the Pd(0)/GO-ILCS catalysts are of exciting potential in the field of hydrogen energy. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.