• 文献标题:   ZSM-5-Supported Graphene-Encapsulated Nickel Nanoparticles: Formation, Properties, and Exceptional Performance in Lipid Hydrogenation
  • 文献类型:   Article
  • 作  者:   LI M, FU JY, LV PM, ZHANG XF, LIU XC, ZENG QY, YANG LM, WANG ZM, YUAN ZH
  • 作者关键词:   graphene, hydrogenation, jet fuel, nickel los, nickel agglomeration
  • 出版物名称:   ACS SUSTAINABLE CHEMISTRY ENGINEERING
  • ISSN:   2168-0485
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   0
  • DOI:   10.1021/acssuschemeng.0c03559
  • 出版年:   2020

▎ 摘  要

Graphene-encapsulated nickel nanoparticles (Ni@C) were loaded on Zeolite Socony Mobil (ZSM)-5 for lipid hydrogenation to produce biojet fuel. Ni@C and ZSM-5 exhibit an efficient and synergistic catalytic activity, and the strong chemical interaction between graphene and nickel significantly improves the hydrogenation capacity of the catalyst. The graphene layers strengthened the dispersion of nickel, reduced the size of Ni@C to similar to 3.6 nm, and kept the valence state of nickel at 0. According to the hydrogenation tests, the conversion of oleic acid to jet fuel could reach 98.59% with only 3 wt % nickel loading amount. Furthermore, Ni@C/ZSM-5 shows excellent resistance to nickel agglomeration and loss.