▎ 摘　　要

With the rapid development of electronics and portable devices, polymer nanocomposites with high through-plane thermal conductivity (TC) are urgently needed. In this work, we fabricated graphene nanosheets-perfluoroalkoxy (GNs-PFA) composite sheets with high through-plane TCs via hot-pressing followed by mechanical machining. When the GNs content exceeded 10 wt%, GNs were vertically aligned in the PFA matrix, and the through-plane TCs of nanocomposites were 10-15 times higher than their in-plane TCs. In particular, the composite with 30 wt% GNs exhibited a through-plane TC of 25.57 W/(m.K), which was 9700% higher than that of pure PFA. The composite with 30 wt% GNs was attached to the surface of a high-power light-emitting diode (LED) to assess its heat-dissipation capability. The composite with vertically aligned GNs lowered the LED surface temperature by approximately 16 degrees C compared with pure PFA. Our facile, low-cost method allows for the large-scale production of GNs-PFA nanocomposites with high through-plane TCs, which can be used in various thermal-management applications.