• 文献标题:   Magnetic ZnFe2O4@chitosan encapsulated in graphene oxide for adsorptive removal of organic dye
  • 文献类型:   Article
  • 作  者:   WU XL, XIAO PY, ZHONG SX, FANG KM, LIN HJ, CHEN JR
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Zhejiang Normal Univ
  • 被引频次:   7
  • DOI:   10.1039/c7ra04100d
  • 出版年:   2017

▎ 摘  要

Graphene-based multifunctional composites were prepared by encapsulating of magnetic ZnFe2O4@chitosan (ZnFe2O4@CS) particles into graphene oxide (GO) layers. The obtained ZnFe2O4@CS/GO were characterized using scanning electron microscopy, X-ray diffraction, Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. Adsorption of basic fuchsin (BF) onto the ZnFe2O4@CS/GO was investigated using pH, adsorption time, initial BF concentration and temperature. Kinetic data and adsorption isotherms were better fitted by a pseudo-second-order kinetic model and Langmuir isotherm model, respectively. The values of activation parameters such as free energy (Delta G, -14.02 to -16.56 kJ mol (1)), enthalpy (Delta H, 23.27 kJ mol (1)) and entropy (Delta S, 127.75 J mol (1) K (1)) were calculated, suggesting that the adsorption was a spontaneous, favorable and endothermic process in nature. The results demonstrated that the ZnFe2O4@CS/GO composites are potentially suitable materials for the removal of organic dyes from large volumes of wastewater.