• 文献标题:   Bipyrene-Functionalized Graphene as a "Turn-On" Fluorescence Sensor for Manganese(II) Ions in Living cells
  • 文献类型:   Article
  • 作  者:   MAO XW, SU HY, TIAN DM, LI HB, YANG RH
  • 作者关键词:   graphene, fluorescence, turn on, sensor, electron transfer, manganese ii ion
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244 EI 1944-8252
  • 通讯作者地址:   Cent China Normal Univ
  • 被引频次:   55
  • DOI:   10.1021/am3026807
  • 出版年:   2013

▎ 摘  要

1,2-bis-(2-pyren-1-ylmethylamino-ethoxy) ethane (NPEY) was synthesized and brought to the surface of graphene nanosheets (GNs) via pi-pi stacking, which provided a simple and convenient route for processing "turn-on" fluorescent sensor by simply mixing the diluted aqueous solutions of both components. The synthesized NPEY modified graphene nanosheets (NPEY-GNs) not only allows good selectivity toward Mn2+ with the detection limit of 4.6 x 10(-5) M, but also shows "turn-on" response for Mn2+ both in vitro and in living cells. These sensing capabilities of NPEY-GNs in living cells make it a robust candidate for many biological fields, such as intracellular tracking, intracellular imaging, etc.