• 文献标题:   Graphene Liquid Marbles as Photothermal Miniature Reactors for Reaction Kinetics Modulation
  • 文献类型:   Article
  • 作  者:   GAO W, LEE HK, HOBLEY J, LIU TX, PHANG IY, LING XY
  • 作者关键词:   graphene, liquid marble, miniature reactor, photothermal reaction, reaction kinetics modulation
  • 出版物名称:   ANGEWANDTE CHEMIEINTERNATIONAL EDITION
  • ISSN:   1433-7851 EI 1521-3773
  • 通讯作者地址:   Nanyang Technol Univ
  • 被引频次:   46
  • DOI:   10.1002/anie.201412103
  • 出版年:   2015

▎ 摘  要

We demonstrate the fabrication of graphene liquid marbles as photothermal miniature reactors with precise temperature control for reaction kinetics modulation. Graphene liquid marbles show rapid and highly reproducible photothermal behavior while maintaining their excellent mechanical robustness. By tuning the applied laser power, swift regulation of graphene liquid marble's surface temperature between 21-135 degrees C and its encapsulated water temperature between 21-74 degrees C are demonstrated. The temperature regulation modulates the reaction kinetics in our graphene liquid marble, achieving a 12-fold superior reaction rate constant for methylene blue degradation than at room temperature.