• 文献标题:   Eu-Based MOF/graphene oxide composite: a novel photocatalyst for the oxidation of benzyl alcohol using water as oxygen source
  • 文献类型:   Article
  • 作  者:   CAI J, LU JY, CHEN QY, QU LL, LU YQ, GAO GF
  • 作者关键词:  
  • 出版物名称:   NEW JOURNAL OF CHEMISTRY
  • ISSN:   1144-0546 EI 1369-9261
  • 通讯作者地址:   Jiangsu Univ
  • 被引频次:   10
  • DOI:   10.1039/c7nj00501f
  • 出版年:   2017

▎ 摘  要

A novel Eu metal-organic framework graphene oxide composite noted as MOF@GO has been synthesized and successfully employed as a photocatalyst for the oxidation of benzyl alcohol using water as an oxygen source. The results show that graphene oxide (GO) not only acts as a structure-directing agent in controlling the morphology of MIL@GO composites but also minimizes the recombination of photogenerated electron-hole pairs to enhance photocatalytic activity. A possible photocatalytic reaction mechanism shows that water is essential for the photocatalytic oxidation, reacting with photo-generated holes to produce molecular oxygen or other active species intermediate in the oxidation of benzyl alcohol.