• 文献标题:   In situ modification of Co-MOF with graphene oxide for enhanced photocatalytic hydrogen production
  • 文献类型:   Article
  • 作  者:   EJSMONT A, LEWANDOWSKAANDRALOJC A, HAUZA K, GOSCIANSKA J
  • 作者关键词:   photocatalysi, metalorganic framework, cobalt specie, hydrogen generation, xps analysi
  • 出版物名称:   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • ISSN:   0360-3199 EI 1879-3487
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.ijhydene.2022.12.084 EA FEB 2023
  • 出版年:   2023

▎ 摘  要

Metal-organic frameworks (MOFs) are one of the most promising precursors for the fabrication of advanced photocatalysts. In this report, we present a stable in water MOF based on earth-abundant cobalt (Co-BDC) as a highly active catalyst for visible-light-driven H2 generation. The rate of H2 production sensitized by eosin Y (EY) over Co-BDC reached 14.5 mmol g-1 h-1. By in situ addition of graphene oxide suspension to the photocatalytic system, the hydrogen production efficiency was further enhanced by a factor of 6.6. (c) 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.