• 文献标题:   Adsorption of naphthalene and its derivatives on magnetic graphene composites and the mechanism investigation
  • 文献类型:   Article
  • 作  者:   YANG X, LI JX, WEN T, REN XM, HUANG YS, WANG XK
  • 作者关键词:   graphene, naphthalene, adsorption mechanism
  • 出版物名称:   COLLOIDS SURFACES APHYSICOCHEMICAL ENGINEERING ASPECTS
  • ISSN:   0927-7757
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   106
  • DOI:   10.1016/j.colsurfa.2012.11.063
  • 出版年:   2013

▎ 摘  要

Reduced graphene oxide/iron oxide (GO/FeO center dot Fe2O3) composites were prepared as super adsorbent to adsorb 1-naphthylamine, 1-naphthol and naphthalene with different polaritiy. The adsorption capacity was found in the order of naphthalene < 1-naphthol < 1-naphthylamine. Electron-donor-acceptor (EDA) interaction was proposed to be the primary mechanism for the adsorption of aromatic compounds, and the adsorption capacity increased with increasing dipole moment. Compared with multi-walled carbon nanotubes/iron oxide (MWCNTs/FeO center dot Fe2O3), we found the morphology of adsorbents played an important role in the adsorption for these aromatic compounds. Thermodynamic experiments further indicated that the adsorption processes were endothermic and spontaneous. (C) 2012 Elsevier B.V. All rights reserved.