• 文献标题:   Ultrasonic synthesis of CoO/graphene nanohybrids as high performance anode materials for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   CHEN BD, PENG CX, CUI Z
  • 作者关键词:   lithiumion battery, graphene, coo, anode material, ultrasonic synthesi
  • 出版物名称:   TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
  • ISSN:   1003-6326 EI 2210-3384
  • 通讯作者地址:   Tongji Univ
  • 被引频次:   19
  • DOI:   10.1016/S1003-6326(11)61494-5
  • 出版年:   2012

▎ 摘  要

A facile ultrasonic method was used to synthesize CoO/graphene nanohybrids by employing Co-4(CO)(12) as a cobalt precursor. The nanohybrids were characterized by SEM, TEM and XPS, and the results show that CoO nanoparticles (3-5 nm) distribute uniformly on the surface of graphene. The CoO/graphene nanohybrids display high performance as an anode material for lithium-ion battery, such as high reversible lithium storage capacity (650 mA.h/g after 50 cycles, almost twice that of commercial graphite anode), high coulombic efficiency (over 95%) and excellent cycling stability. The extraordinary performance arises from the structure of the nanohybrids: the nanosized CoO particles with high dispersity on conductive graphene substrates are beneficial for lithium-ion insertion/extraction, shortening diffusion length for lithium ions and improving conductivity, thus the lithium storage performance was improved.