• 文献标题:   A facile synthesis of cellulose acetate reinforced graphene oxide nanosheets as proton exchange membranes for fuel cell applications
  • 文献类型:   Article
  • 作  者:   MADIH K, ELSHAZLY AH, ELKADY MF, AZIZ AN, YOUSSEF MEE, KHALIFA R
  • 作者关键词:   keywordscellulose acetate, proton conductivity, nafion 212
  • 出版物名称:   JOURNAL OF SAUDI CHEMICAL SOCIETY
  • ISSN:   1319-6103 EI 2212-4640
  • 通讯作者地址:  
  • 被引频次:   6
  • DOI:   10.1016/j.jscs.2022.1014351319-6103
  • 出版年:   2022

▎ 摘  要

In this work, for the first time, a simple casting process is used to create an efficient and highly stable cellulose acetate (CA) based membrane with dispersive graphene oxide nanosheets (GO). The successful preparation of GO and its integration into the polymer matrix was verified by structural and morphological characterization using FTIR, TEM, SEM, and XRD. Furthermore, the impact of GO nanosheets and their content on the composite membranes' physicochemical properties is investigated. The water uptake increased up to 24% as the concentration of GO increased, while the ion exchange capacity increased threefold compared to the blank CA membrane. Additionally, increasing GO loading also enhanced the proton conductivity and the tensile strength of the developed membranes. The homogeneous CA/GO nanocomposite membranes with GO filler amounts ranging from 0.3 to 0.8 wt% were found to have excellent proton conductivity varying from 9.2 to 15.5 mS/cm compared to 6.94 mS/cm for Nafion 212. Further, as systematically studied and compared in membrane performance, the overall power density of the membrane electrode assembly (MEA) with GO content was increased up to 519 mW/cm2 compared to