• 文献标题:   4-Methoxyphenyl grafted onto graphene quantum dots surface via diazonium chemistry method
  • 文献类型:   Article
  • 作  者:   LUO PH, GUAN XF, YU YL, LI XY
  • 作者关键词:   graphene quantum dot, chemical modification, carbon material, luminescence
  • 出版物名称:   OPTICAL QUANTUM ELECTRONICS
  • ISSN:   0306-8919 EI 1572-817X
  • 通讯作者地址:   Fujian Jiangxia Univ
  • 被引频次:   0
  • DOI:   10.1007/s11082-018-1544-7
  • 出版年:   2018

▎ 摘  要

Chemical modifacation is effective method to change surface state of graphene quantum dots (GQDs). GQDs modified with various functional groups exhibit multicolor photoluminescence (PL). Here, 4-methoxyphenyl (MP) group, with electron donating methoxy as substituent on aromatic ring, was grafted onto GQDs surface via a diazonium chemistry method. After modification, the average diameter of GQDs was decreased from 3.3 to 2.5 nm, and their PL was blue-shifted 40 nm relative to raw GQDs (R-GQDs). The result is similar to that of GQDs modified with phenyl (P), 4-carboxyphenyl (CP), 5-sulfonaphthyl (SN) and 4-sulfophenyl (SP), which are aryl groups without substituent and with electron withdrawing substituent, previously. Therefore, properties of substituent groups located at aryl do not obviously change PL behavior of aryl-modified GQDs.