• 文献标题:   Nano-size NiS particles anchored on nitrogen-doped reduced graphene oxide for superior sodium storage
  • 文献类型:   Article
  • 作  者:   ZHANG SJ, WANG RR, CAO RG, FANG F
  • 作者关键词:   sodiumion batterie, nickel sulfide, nanoparticle, rgo nanosheet
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:  
  • 被引频次:   5
  • DOI:   10.1016/j.jallcom.2021.161316 EA AUG 2021
  • 出版年:   2021

▎ 摘  要

Nickel sulfides are regarded as promising anode materials for sodium-ion battery due to their natural abundance and high theoretical capacity. However, they are subjected to poor conductivity and severe volume variation during charging/discharging process, leading to sluggish kinetics and rapid capacity loss. To address these dilemmas, a hybrid composite consisting of nickel sulfide nanoparticles uniformly anchored on the nitrogen-doped reduced graphene oxide (NiS@N-rGO) has been fabricated through a facile sulfidation of ultrathin Ni(OH)2/rGO precursor. Owing to the high electronic conductivity of composite, alleviated volume expansion and accelerated ion diffusion, the NiS@N-rGO composite exhibits an initial specific capacity as high as 872.8 mAh g-1 at a current density of 0.2 A g-1 and maintain 300 mAh g-1 at a current density of 1 A g-1 after 300 cycles when employed as anode in sodium-ion batteries (SIBs). This work may present a new avenue in the design of electrode materials with excellent performance for SIBs in the future. (c) 2021 Published by Elsevier B.V.