• 文献标题:   Preparation and Application of Water-in-Oil Emulsions Stabilized by Modified Graphene Oxide
  • 文献类型:   Article
  • 作  者:   FEI XM, XIA L, CHEN MQ, WEI W, LUO J, LIU XY
  • 作者关键词:   modified graphene oxide, pickering emulsion, waterinoil emulsion, nanocomposite
  • 出版物名称:   MATERIALS
  • ISSN:   1996-1944
  • 通讯作者地址:   Jiangnan Univ
  • 被引频次:   9
  • DOI:   10.3390/ma9090731
  • 出版年:   2016

▎ 摘  要

A series of alkyl chain modified graphene oxides (AmGO) with different alkyl chain length and content was fabricated using a reducing reaction between graphene oxide (GO) and alkyl amine. Then AmGO was used as a graphene-based particle emulsifier to stabilize Pickering emulsion. Compared with the emulsion stabilized by GO, which was oil-in-water type, all the emulsions stabilized by AmGO were water-in-oil type. The effects of alkyl chain length and alkyl chain content on the emulsion properties of AmGO were investigated. The emulsions stabilized by AmGO showed good stability within a wide range of pH (from pH = 1 to pH = 13) and salt concentrations (from 0.1 to 1000 mM). In addition, the application of water-in-oil emulsions stabilized by AmGO was investigated. AmGO/polyaniline nanocomposite (AmGO/PANi) was prepared through an emulsion approach, and its supercapacitor performance was investigated. This research broadens the application of AmGO as a water-in-oil type emulsion stabilizer and in preparing graphene-based functional materials.