• 文献标题:   A Highly Sensitive Carbendazim Sensor Based on Electrochemically Reduced Graphene Oxide
  • 文献类型:   Article
  • 作  者:   DONG XY, QIU BJ, YANG XW, JIANG D, WANG K
  • 作者关键词:   electrochemically reduced graphene oxide, carbendazim, differential pulse voltammetry, electrochemical sensor
  • 出版物名称:   ELECTROCHEMISTRY
  • ISSN:   1344-3542 EI 2186-2451
  • 通讯作者地址:   Jiangsu Univ
  • 被引频次:   6
  • DOI:   10.5796/electrochemistry.82.1061
  • 出版年:   2014

▎ 摘  要

A simple method for direct and quantitative determination of carbendazim using electrochemically reduced graphene oxide modified glassy carbon electrode (ERGO/GCE) has been developed. The obtained electrode was characterized using scanning electron microscopy, Raman spectroscopy, cyclic voltammetry and differential pulse voltammetry. Compared to bare and graphene oxide modified electrodes (GO/GCE), the ERGO/GCE not only significantly shifted to a lower positive potential, but also noticeably enhanced the current response. The resulting carbendazim sensor showed a wide linear range (2.0 nM to 400 nM) and a low detection limit (1.0 nM). In addition, the proposed sensor has excellent selectivity, good stability and can be successfully applied in soil sample. The ERGO, which was obtained by facile, cost-effective method, could provide a promising platform to develop excellent electrochemical sensors for detecting carbendazim. (C) The Electrochemical Society of Japan, All rights reserved.