• 文献标题:   A Facile Synthesis of Low-Defect-Density Graphene/MnO2 Composite and Its Electrochemical Performance
  • 文献类型:   Article
  • 作  者:   HE GY, YUAN Y, WANG L, CHEN HQ, SUN XQ, WANG X
  • 作者关键词:   graphene, mno2, nanoparticle, composite, electrochemical performance
  • 出版物名称:   JOURNAL OF NANOSCIENCE NANOTECHNOLOGY
  • ISSN:   1533-4880 EI 1533-4899
  • 通讯作者地址:   Changzhou Univ
  • 被引频次:   1
  • DOI:   10.1166/jnn.2013.6902
  • 出版年:   2013

▎ 摘  要

A facile chemical strategy was developed to anchor MnO2 nanoparticles on the surface of graphene sheet. Compared with literature, this approach requires neither extra pretreatment of acid functionalization of graphite nor any post-treatment for the conductivity compensation. Graphene sheet serves as both the nucleation center of the MnO2 nanoparticles and high-efficiency miniature current collectors, endowing an effective rise in electrochemical performance of the overall system. Meanwhile, few layers graphene restrain the aggregation of MnO2 nanoparticles and act as template for the "sandwich structure," which boosts accessible surface areas for the high rates charge and discharge processes. The internal resistance drops of the electrode were small, which is propitious to the high discharge delivery. And the nanocomposite with the unique structure displayed a specific capacitance as high as 340.5 F g(-1). Moreover, the capacitance decrease was only 3.7% after 1000 cycles.