• 文献标题:   Analytical Applicability of Graphene-Modified Electrode in Sunset Yellow Electrochemical Assay
  • 文献类型:   Article
  • 作  者:   MAGERUSAN L, POGACEAN F, COZAR BI, PRUNEANU S
  • 作者关键词:   sunset yellow, graphenemodified electrode, electrochemical detection
  • 出版物名称:   SENSORS
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.3390/s23042160
  • 出版年:   2023

▎ 摘  要

Due to the recent increase in average living standards, food safety has caught public attention. It is necessary to conduct a qualitative and quantitative rapid test of prohibited food additives since the inclusion of food additives or the improper usage of synthetic dyes can negatively impact on the human health. Herein, a highly sensitive method for Sunset Yellow detection based on a glassy carbon electrode modified with few-layer graphenes was proposed. The electrochemical behavior of SY at the GR-exf/GCE modified surface was investigated by Cyclic Voltammetry, Square Wave Voltammetry, Electrochemical Impedance Spectroscopy and Amperometry. The influences of pH, scan rate, and interfering species were studied. Under optimized conditions, the developed sensor shows good linearity over a broad SY concentration range, e.g., 0.028-30 mu M, with a low limit of detection (LOD = 0.0085 mu M) and quantification (LOQ = 0.028 mu M) (data obtained by amperometric technique). Furthermore, the modified electrode shows good selectivity, precision and sensitivity and has been successfully applied for SY quantification from commercially available pharmaceutical formulation as well as from candy bars and orange juice.