• 文献标题:   Postcomposition Preparation and Supercapacitive Properties of Polyaniline Nanotube/Graphene Oxide Composites with Interfacial Electrostatic Interaction
  • 文献类型:   Article
  • 作  者:   ZHANG Y, XIONG SX, WANG YY, WU BH, CHU J, WANG XQ, ZHANG RL, GONG M, LI Z, QU MN, CHEN ZM
  • 作者关键词:   polyaniline nanotube, graphene oxide, electrostatic adsorption, supercapacitance
  • 出版物名称:   JOURNAL OF ELECTRONIC MATERIALS
  • ISSN:   0361-5235 EI 1543-186X
  • 通讯作者地址:   Xian Univ Sci Technol
  • 被引频次:   0
  • DOI:   10.1007/s11664-020-08128-4 EA APR 2020
  • 出版年:   2020

▎ 摘  要

Polyaniline nanotubes (PANI-T) and graphene oxide (GO) have been compounded by a postcomposition method with the assistance of electrostatic adsorption. Using this so-called postcomposition method, both the electric double-layer capacitance of the GO and the pseudocapacitance of the conducting polymer can be utilized. PANI-T prepared by a rapid mixing method was positively charged by pretreatment with (3-aminopropyl)triethoxysilane (APTES). PANI/GO composites were obtained by mixing the positively charged PANI-T and negatively charge GO with the assistance of electrostatic attraction. Charge-discharge measurements in 1 mol L-1 H2SO4 aqueous electrolyte revealed that the specific capacitance of PANI-T/GO-10% could reach 1220 F g(-1) at a current density of 0.5 A g(-1), being much higher than the value of 648 F g(-1) for PANI-T. After 500 cycles of charge-discharge testing, the composite retained 97% of its capacitance. These enhanced supercapacitive properties can be attributed to the two types of energy storage mechanism and the electrostatic interaction between GO and PANI-T. Preparation of such PANI-T/GO composite electrode materials by electrostatic adsorption thus provides an efficient approach for improvement of the supercapacitive properties of conducting polymers or metal oxides.