• 文献标题:   Synthesis and catalytic application of Pd/PdO/Fe3O4@polymer-like graphene quantum dots
  • 文献类型:   Article
  • 作  者:   KESHIPOUR S, ALAZMI A
  • 作者关键词:   citric acid, fast synthesis graphene, oxidation, pd catalysi, poly graphene quantum dot
  • 出版物名称:   APPLIED ORGANOMETALLIC CHEMISTRY
  • ISSN:   0268-2605 EI 1099-0739
  • 通讯作者地址:   Urmia Univ
  • 被引频次:   1
  • DOI:   10.1002/aoc.5311 EA NOV 2019
  • 出版年:   2020

▎ 摘  要

A novel approach was achieved for growing citric acid towards polymer-like graphene quantum dots (PGQD) with high efficiency in the presence of sodium hydroxide as a base catalyst. This protocol is completely safe, simple, fast, and efficient by a bottom up strategy. Thermal treatment of a mixture containing citric acid with NaOH at 300 degrees C gave PGQD during 5 min. The reaction afforded a new heterogeneous catalyst, Pd/PdO/Fe3O4@PGQD, in the presence of Pd and Fe3O4. The magnetically recoverable catalyst showed high activity in the oxidation of alkylarenes and alcohols using H2O2 as a green oxidant at room temperature. Comparison of the results with previous reports showed the efficiency of the catalyst to have high turnover numbers in mild reaction conditions.