• 文献标题:   Examining the contribution of factors affecting the electrical behavior of poly(methyl methacrylate)/graphene nanoplatelets composites
  • 文献类型:   Article
  • 作  者:   LUO XL, SCHUBERT DW
  • 作者关键词:   film, morphology, nanostructured polymer, nanotube, graphene fullerene, theory modeling
  • 出版物名称:   JOURNAL OF APPLIED POLYMER SCIENCE
  • ISSN:   0021-8995 EI 1097-4628
  • 通讯作者地址:  
  • 被引频次:   4
  • DOI:   10.1002/app.50694 EA MAR 2021
  • 出版年:   2021

▎ 摘  要

In this study, poly(methyl methacrylate) (PMMA)/graphene nanoplatelets (GNPs) conductive composite films with different morphologies were fabricated from the same constituent materials using four fabrication techniques, solution casting (SC), SC followed by hot pressing (SCP), melt mixing followed by SC (MSC), and melt mixing followed by hot pressing (MP). Morphologies of dispersed GNPs and electrical properties in both in-plane and perpendicular direction were investigated and compared systematically. The corresponding percolation thresholds (phi(c)) of the composites varied from 0.42 +/- 0.13 vol% to 3.26 +/- 0.48 vol%. The conductivities varied up to two orders of magnitude and decreased in the sequence of SC > MSC > SCP > MP. These variations were explained in terms of GNPs size, GNPs orientation, distribution and dispersion state of fillers. The contribution of the above factors in each procedure were discerned individually, the results were discussed and compared with other experimental studies and simulations as well.