• 文献标题:   Scanning probe microscopy study of exfoliated oxidized graphene sheets
  • 文献类型:   Article
  • 作  者:   PANDEY D, REIFENBERGER R, PINER R
  • 作者关键词:   atomic force microscopy, lateral force microscopy, scanning tunneling microscopy, scanning tunneling spectroscopy, highly oriented pyrolitic graphite, oxidized graphene og
  • 出版物名称:   SURFACE SCIENCE
  • ISSN:   0039-6028
  • 通讯作者地址:   Purdue Univ
  • 被引频次:   133
  • DOI:   10.1016/j.susc.2008.02.025
  • 出版年:   2008

▎ 摘  要

Exfoliated oxidized graphene (OG) sheets, suspended in an aqueous solution, were deposited on freshly cleaved HOPG and studied by ambient AFM and UHV STM. The AFM images revealed oxidized graphene sheets with a lateral dimension of similar to 5-10 mu m. The oxidized graphene sheets exhibited different thicknesses and were found to conformally coat the HOPG substrate. Wrinkles and folds induced by the deposition process were clearly observed. Phase imaging and lateral force microscopy showed distinct contrast between the oxidized graphene and the underlying HOPG substrate. The UHV STM studies of oxidized graphene revealed atomic scale periodicity showing a (0.273 +/- 0.008) nm x (0.406 +/- 0.013) nm unit cell over distances spanning few nanometers. This periodicity is identified with oxygen atoms bound to the oxidized graphene sheet. I(V) data were taken from oxidized graphene sheets and compared to similar data obtained from bulk HOPG. The dI/dV data from oxidized graphene reveals a reduction in the local density of states for bias voltages in the range of +/- 0.1 V. Published by Elsevier B.V.