• 文献标题:   Graphene-nickel/n-carboxylic acids composites as form-stable phase change materials for thermal energy storage
  • 文献类型:   Article
  • 作  者:   LIANG WD, ZHANG GD, SUN HX, CHEN PS, ZHU ZQ, LI A
  • 作者关键词:   graphene, nickel foam, pcm, superoleophilicity, latent heat
  • 出版物名称:   SOLAR ENERGY MATERIALS SOLAR CELLS
  • ISSN:   0927-0248 EI 1879-3398
  • 通讯作者地址:   Lanzhou Univ Technol
  • 被引频次:   43
  • DOI:   10.1016/j.solmat.2014.09.032
  • 出版年:   2015

▎ 摘  要

Superoleophilic graphene-nickel foam (PDMS-G-NF), which was prepared by coating graphene nanosheets onto nickel foam followed by surface modification with polydimethylsiloxane (PDMS), was used as porous supporting material to prepare form-stable phase change materials (PCMs) composites. Owing to the strong hydrophobic and superhydrophilic wettability of PDMS-G-NF, PCMs can be absorbed spontaneously into PDMS-G-NF and can stay stable without leakage even over their melting points. The incorporation of PCMs into PDMS-G-NF does not change the crystal structure but lowers the crystallinity size of PCMs in the composites, which is confirmed by X-ray powder diffraction (XRD) analysis. The latent heat of PDMS-G-NF/PCM composites was measured in the range of 423-123.41 kJ kg(-1). Taking advantages of the simple process and good stability the PDMS-G-NF should be ideal candidates as an alternative to traditional PCMs, which may have great potentials for renewable energy saving applications. (C) 2014 Elsevier B.V. All rights reserved.