• 文献标题:   Bifacial Multilayer Graphene Float Transfer
  • 文献类型:   Article
  • 作  者:   ANDRADE JA, FOLKSON J, BOUKHICHA M, CARR AJ, EISAMAN MD
  • 作者关键词:   cvd graphene, freestanding graphene, graphenepolymer film, graphene transfer, multilayer graphene
  • 出版物名称:   ADVANCED FUNCTIONAL MATERIALS
  • ISSN:   1616-301X EI 1616-3028
  • 通讯作者地址:   SUNY Stony Brook
  • 被引频次:   0
  • DOI:   10.1002/adfm.202005103 EA SEP 2020
  • 出版年:   2020

▎ 摘  要

A method for graphene transfer which is referred to as "bifacial transfer" that allows transfer of multilayer chemical vapor deposition (CVD) graphene from both sides of a native metal substrate, such as an as-received nickel catalyst, is presented. In traditional transfer methods, the graphene on the "non-preferred" side, that is, the bottom of the substrate, is removed with oxygen plasma before removal of the metal catalyst in etchant solution. Although this treatment prevents undesired aggregation of the graphene films, it fails to utilize both sides of CVD-grown graphene. The bifacial transfer method reduces the cost of multilayer graphene by allowing the transfer of graphene from both sides of the substrate. The quality of graphene transferred from both sides onto target glass and polymer substrates is compared. The results of optical microscopy, confocal Raman spectroscopy, atomic force microscopy, and electronic transport measurements suggest that the quality of the multilayer graphene on the "non-preferred" side does not differ significantly from that of the "preferred" side. This method will allow more efficient and cost-effective use of graphene by doubling the usable graphene per area of growth substrate, and by eliminating the need for intermediate sacrificial transfer substrates such as poly(methyl methacrylate).