• 文献标题:   Highly Stable LiI/Active Graphene Composite Cathodes for Efficient Lithium-Iodine Batteries
  • 文献类型:   Article
  • 作  者:   ZHANG Q, LI FH, ZHANG XX, WANG HB, LI FC, GUO ZY, ZHANG Z
  • 作者关键词:   lii2 battery, lii, active graphene, uniform dispersion, highly stable
  • 出版物名称:   JOURNAL OF THE ELECTROCHEMICAL SOCIETY
  • ISSN:   0013-4651 EI 1945-7111
  • 通讯作者地址:  
  • 被引频次:   3
  • DOI:   10.1149/1945-7111/abf4af
  • 出版年:   2021

▎ 摘  要

Lithium iodide (LiI) is regarded as a promising cathode material for lithium-iodine (Li-I-2) batteries in terms of its high merits, high theoretical specific capacity of 200 mAh g(-1) and good compatibility with lithium metal-free anodes. However, LiI suffers from poor cycling stability and rate capability resulted from the serious shuttle effect of iodide and its low conductivity. Herein, a commercial active graphene (AG) with high pore volume, high specific surface area and good conductivity is employed as a host material for lithium iodide (LiI). X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) characterizations of the resultant LiI/AG composites indicate that LiI uniformly disperses in the nanopores of AG. The LiI/AG composite cathode with 40 wt.% LiI shows enhanced electrochemical performance including excellent cycling stability and high Coulombic efficiency. This work demonstrates a simple strategy to fabricate efficient composite cathodes for high-performance rechargeable Li-I-2 batteries.