• 文献标题:   Graphene-Wrapped ZnMn2O4 Nanoparticles with Enhanced Performance as Lithium-Ion Battery Anode Materials
  • 文献类型:   Article
  • 作  者:   SUN M, LI SJ, ZOU JJ, CUI ZP, ZHANG QY, SCHIETTEKATTE F, BARBA D, LIU B, WANG YQ
  • 作者关键词:   lib, znmn2o4 np, rgo, electrochemical performance
  • 出版物名称:   NANO
  • ISSN:   1793-2920 EI 1793-7094
  • 通讯作者地址:   Qingdao Univ
  • 被引频次:   0
  • DOI:   10.1142/S1793292020501179
  • 出版年:   2020

▎ 摘  要

ZnMn2O4 nanoparticles (NPs) wrapped by reduced graphene oxide (rGO) were fabricated via a two-step solvothermal method and used as an anode material for lithium-ion batteries (LIBs). Compared to pure ZnMn2O4, the ZnMn2O4 NPs/rGO composites deliver higher capacities of 1230 mAh g(-1) and 578 mAh g(-1) after 200 cycles at a current density of 100 mA g(-1) and 500 mA g(-1), respectively. The enhanced electrochemical performance of ZnMn2O4 NPs/rGO composites is mainly attributed to a distinctive structure (ZnMn2O4 NPs surrounded by flexible rGO), which can promote the diffusion of Li+, accelerate the transport of electrons and buffer volume expansion during the Li+ insertion/extraction process. Furthermore, the rGO sheets can effectively prevent the agglomeration of ZnMn2O4 NPs, thus, improving structural stability of the composites. The excellent electrochemical performance indicates that such ZnMn2O4 NPs/rGO composite structure has a great potential for high-performance LIBs.