• 文献标题:   The reduction of graphene oxide with hydrazine: elucidating its reductive capability based on a reaction-model approach
  • 文献类型:   Article
  • 作  者:   CHUA CK, PUMERA M
  • 作者关键词:  
  • 出版物名称:   CHEMICAL COMMUNICATIONS
  • ISSN:   1359-7345 EI 1364-548X
  • 通讯作者地址:   Nanyang Technol Univ
  • 被引频次:   45
  • DOI:   10.1039/c5cc08170j
  • 出版年:   2016

▎ 摘  要

We have performed an experimental investigation on the effects of hydrazine treatment on graphene oxide via a reaction-model approach. Hydrazine was reacted with small conjugated aromatic compounds containing various oxygen functional groups to mimic the structure of graphene oxide. The hydroxyl and carboxylic groups were not readily removed while carbonyl groups reacted with hydrazine to form the corresponding hydrazone complexes. In the presence of adjacent hydroxyl groups, carboxyl groups underwent thermal decarboxylation.