▎ 摘　　要

Polypyrrole nanospheres were embedded in graphene layers (rGCP) to successfully form threedimensional hierarchical cross-linking structure through simple hydrothermal method. The structure of rGCP composite mainly resulted from the synergistic effect of cetyltrimethyl ammonium bromide and crumpled graphene layers, which was beneficial for achieving large surface area, short ion diffusion pathway, excellent rate performance and cycling stability. As a result, the hybrid rGCP composite exhibited excellent electrochemical performance with a specific capacitance of almost 400 F g(-1) at the scan rate of 1 mV s(-1). Furthermore, even at the high current density of 10 A g(-1), it still retained the capacitance of 243.2 F g(-1), and excellent cycling stability (91.8% capacitance retention even after 5000 cycles). The as-prepared hierarchical hybrid composite has promising potential in electrochemical energy storage. (C) 2015 Elsevier Ltd. All rights reserved.