• 文献标题:   Synthesis and application of sulfonated graphene oxide for the adsorption of uranium(VI) from aqueous solutions
  • 文献类型:   Article
  • 作  者:   ZHANG ZB, QIU YF, DAI Y, WANG PF, GAO B, DONG ZM, CAO XH, LIU YH, LE ZG
  • 作者关键词:   adsorption, uranium vi, graphene oxide, sulfonic acid group
  • 出版物名称:   JOURNAL OF RADIOANALYTICAL NUCLEAR CHEMISTRY
  • ISSN:   0236-5731 EI 1588-2780
  • 通讯作者地址:   East China Inst Technol
  • 被引频次:   15
  • DOI:   10.1007/s10967-016-4813-6
  • 出版年:   2016

▎ 摘  要

In this article, we report a facile one-pot method to prepare sulfonated graphene oxide (GOS) via vapor-solid transfer reaction of graphene oxide (GO). The synthesized GOS were characterized and investigated as an adsorbent for the adsorption of U(VI) from aqueous solutions. The results indicated that the adsorption of U(VI) was strongly dependent on pH and independent of ionic strength. The adsorption process followed the pseudo-second-order kinetics and the adsorption isotherm agreed well with the Langmuir model, having a maximum adsorption capacity of 309.09 mg g(-1). Thermodynamic parameters indicated that the adsorption reaction was an endothermic and spontaneous process.