• 文献标题:   Largely enhanced thermal conductivity of poly (ethylene glycol)/boron nitride composite phase change materials for solar-thermal-electric energy conversion and storage with very low content of graphene nanoplatelets
  • 文献类型:   Article
  • 作  者:   YANG J, TANG LS, BAO RY, BAI L, LIU ZY, YANG W, XIE BH, YANG MB
  • 作者关键词:   phase change material, thermal conductivity, synergistic effect, lighttothermal conversion, lighttoelectric conversion
  • 出版物名称:   CHEMICAL ENGINEERING JOURNAL
  • ISSN:   1385-8947 EI 1873-3212
  • 通讯作者地址:   Sichuan Univ
  • 被引频次:   51
  • DOI:   10.1016/j.cej.2017.01.045
  • 出版年:   2017

▎ 摘  要

Phase change materials (PCMs) with high thermal conductivity and efficient solar energy conversion have recently attracted much attention. However, a facile strategy to enhance thermal conductivity and realize energy conversion and storage is still eagerly desired. In this work, a very low content of graphene nano platelets (GNP) is introduced into poly (ethylene glycol) (PEG)/boron nitride (BN) composite PCM5, resulting in great improvement in thermal conductivity and photoabsorption ability via a facile solution blending process. The presence of GNP contributes to enhancing thermal conductivity and realizing efficient solar energy conversion (including solar-to-thermal and solar-to-electric energy conversion) for the PEG/BN/GNP composite PCMs owing to the formation of improved BN/GNP thermally conductive network and the improvement of sunlight harvesting ability, respectively. Thermophysical properties demonstrate that compared with PEG/BN composite PCM5 at the same BN content, PEG/BN/GNP composite PCMs containing a low GNP content maintain comparable energy storage density. The study sheds light on the realization of solar energy utilization and storage of the organic PCMs requiring high thermal conductivity. (C) 2017 Elsevier B.V. All rights reserved.