• 文献标题:   Highly exposed copper oxide supported on three-dimensional porous reduced graphene oxide for non-enzymatic detection of glucose
  • 文献类型:   Article
  • 作  者:   ZHAO Y, BO XJ, GUO LP
  • 作者关键词:   porous reduced graphene oxide, copper oxide, hydrothermal, nonenzymatic glucose detection
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   NE Normal Univ
  • 被引频次:   38
  • DOI:   10.1016/j.electacta.2015.07.143
  • 出版年:   2015

▎ 摘  要

Copper oxide nanoparticles were anchored on porous reduced graphene oxide (PrGO) by a simple and mild hydrothermal method. The as-prepared product was characterized by X-ray diffraction, N-2 adsorption-desorption isotherms, scanning electron microscopy, and used to build a novel glucose sensor. The CuO/PrGO nanocomposite showed an enhanced electrocatalytic activity to direct glucose oxidation compared with the non-porous reduced graphene oxide-CuO (CuO/rGO). The CuO/PrGO modified glass carbon electrode (CuO/PrGO-GCE) responded linearly to glucose in the range of 0.001 to 6 mM and the detection limit of the transducer was found to be 0.50 mu M. High reproducibility, wide linear range, good anti-interference, stability and enough precision in real sample analysis made it promising for the development of enzyme-free sensors. (C) 2015 Elsevier Ltd. All rights reserved.