• 文献标题:   Polyethylene glycol grafted with carboxylated graphene oxide as a novel interface modifier for polylactic acid/graphene nanocomposites
  • 文献类型:   Article
  • 作  者:   NIU MJ, WANG H, LI J, CHEN HY, LI L, YANG HG, LIU XY, CHEN ZH, LIU HZ, CHEN JZ
  • 作者关键词:   polylactic acid, graphene oxide, carboxylation, polyethylene glycol, mechanical propertie
  • 出版物名称:   ROYAL SOCIETY OPEN SCIENCE
  • ISSN:   2054-5703
  • 通讯作者地址:   Zhengzhou Univ
  • 被引频次:   0
  • DOI:   10.1098/rsos.192154
  • 出版年:   2020

▎ 摘  要

Strength and toughness are both of great importance for the application of polylactic acid (PLA). Unfortunately, these two properties are often contradictory. In this work, an effective and practical strategy is proposed by using carboxylated graphene oxide (GC) grafted with polyethylene glycol (PEG), i.e. GC-g-PEG. The synthesis procedure of GC-g-PEG is firstly optimized. Then, a series of PLA nanocomposites were prepared by the melt blending method via masterbatch. In comparison to that achieved over pure PLA, these nanocomposites are of higher crystallinity, thermal stability and mechanical strength. This is mainly attributed to well-tailored interface and good dispersion. Especially, while retaining the tensile strength of the original PLA, the elongation at break increases by seven times by adding 0.3 wt% GC-g-PEG.