• 文献标题:   Exploration of edge-dependent optical selection rules for graphene nanoribbons
  • 文献类型:   Article
  • 作  者:   CHUNG HC, LEE MH, CHANG CP, LIN MF
  • 作者关键词:  
  • 出版物名称:   OPTICS EXPRESS
  • ISSN:   1094-4087
  • 通讯作者地址:   Natl Cheng Kung Univ
  • 被引频次:   28
  • DOI:   10.1364/OE.19.023350
  • 出版年:   2011

▎ 摘  要

Optical selection rules for one-dimensional graphene nanoribbons are explored based on the tight-binding model. A theoretical explanation, through analyzing the velocity matrix elements and the features of the wavefunctions, can account for the selection rules, which depend on the edge structure of the nanoribbon, i.e., armchair or zigzag edges. The selection rule of armchair nanoribbons is Delta J = J(c) - J(v) = 0, and the optical transitions occur from the conduction to the valence subbands of the same index. Such a selection rule originates in the relationships between two sublattices and between the conduction and valence subbands. On the other hand, zigzag nanoribbons exhibit the selection rule vertical bar Delta J vertical bar = odd, which results from the alternatively changing symmetry property as the subband index increases. Furthermore, an efficient theoretical prediction on transition energies is obtained by the application of selection rules, and the energies of the band-edge states become experimentally attainable via optical measurements. (C) 2011 Optical Society of America