• 文献标题:   Three-dimensional carbon-coated ZnFe2O4 nanospheres/nitrogen-doped graphene aerogels as anode for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   YAO LB, DENG HH, HUANG QA, SU QM, DU GH
  • 作者关键词:   composite, nanostructure, metal oxide, anode, graphene
  • 出版物名称:   CERAMICS INTERNATIONAL
  • ISSN:   0272-8842 EI 1873-3956
  • 通讯作者地址:   Zhejiang Normal Univ
  • 被引频次:   16
  • DOI:   10.1016/j.ceramint.2016.10.034
  • 出版年:   2017

▎ 摘  要

Three-dimensional (3D) porous carbon-coated ZnFe2O4 nanospheres/N-doped graphene aerogels (ZnFe2O4@C/N-G) have been synthesized via a facile hydrothermal method. The obtained ZnFe2O4@C hierarchical nanospheres with a size distribution of 150-210 nm are uniformly encapsulated within the graphene aerogels matrix. The ZnFe2O4@C/N-G composites as anode materials for Li-ion batteries demonstrate a high initial discharge capacity of similar to 1176 mA h g(-1) with an initial coulombic efficiency of similar to 71.1% at a rate of 100 mA g(-1). Moreover, a significantly enhanced reversible capacity of 952 mA h g(-1) is retained after 100 cycles. After being cycled at various rates for 100 cycles, the capacity can reincrease to 955 mA h g(-1) when the specific current returns back to 100 mA g(-1). The improved electrochemical performance is attributed to the unique architectures of the carbon layer (similar to 2 to 4 nm) and 3D porous N-doped graphene aerogels.