• 文献标题:   Holey reduced graphene oxide/carbon nanotube/LiMn0.7Fe0.3PO4 composite cathode for high-performance lithium batteries
  • 文献类型:   Article
  • 作  者:   DING D, MAEYOSHI Y, KUBOTA M, WAKASUGI J, KANAMURA K, ABE H
  • 作者关键词:   holey graphene, carbon nanotube, limn0.7fe0.3po4, composite cathode, lithium battery
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Tokyo Metropolitan Univ
  • 被引频次:   3
  • DOI:   10.1016/j.jpowsour.2019.227553
  • 出版年:   2020

▎ 摘  要

Graphene has attracted considerable attention as the conductive agent for lithium batteries by providing a superior interfacial contact. However, the wrapping of active materials by the large area of graphene sheets may hinder the transportation of Li+ between active particles and electrolyte, especially at a high charge/discharge rates. Herein, holey graphene oxide (h-GO), which is made by a green wet ball-miffing of GO in one step without using any catalysts or chemicals, is combined with carbon nanotubes (CNTs) and LiMn0.7Fe0.3PO4 (LMFP) to make a composite cathode for lithium batteries. Results show that after the electrochemical reduction, the LMFP cathode with h-GO/CNT shows remarkedly improved electrochemical performances due to the facilitated Li+ transport pathway, compared to that with conventional GO/CNT. For example, LMFP/h-GO/CNT composite cathode can achieve a discharge capacity of 112 mAh g(-1) when discharged at 20 C, while LMFP electrode with conventional GO/CNT only shows a discharge capacity of 35 mAh g(-1). This study provides a new approach for fabricating holey graphene and can open up new possibilities for applications on power sources.