• 文献标题:   Facile synthesis of bimetallic alloyed Pt-Pd nanocubes on reduced graphene oxide with enhanced eletrocatalytic properties
  • 文献类型:   Article
  • 作  者:   LV JJ, ZHENG JN, CHEN LL, LIN M, WANG AJ, CHEN JR, FENG JJ
  • 作者关键词:   nanocube, reduced graphene oxide, electrocatalysi, ethanol oxidation, oxygen reduction reaction
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Zhejiang Normal Univ
  • 被引频次:   21
  • DOI:   10.1016/j.electacta.2014.07.128
  • 出版年:   2014

▎ 摘  要

In this work, a one-pot solvothermal method was developed for large-scaled synthesis of well-defined bimetallic alloyed Pt-Pd nanocubes uniformly supported on reduced graphene oxide nanosheets (Pt-Pd nanocubes/RGOs). Herein, poly(vinylpyrrolidone) (PVP) and KI were employed as a capping agent and a structure-directing additive, respectively, and N, N-dimethylformamide (DMF) is used as a solvent and a reducing agent. The as-prepared Pt-Pd nanocubes/RGOs exhibited the enlarged electrochemically active surface area, enhanced electrocatalytic activity, and improved stability for ethanol oxidation reaction (EOR) and oxygen reduction reaction (ORR), compared with commercial Pt-C (10 wt %). (C) 2014 Elsevier Ltd. All rights reserved.