• 文献标题:   Infrared spectroscopy of large scale single layer graphene on self assembled organic monolayer
  • 文献类型:   Article
  • 作  者:   KIM NW, KIM JY, LEE C, KIM SJ, HONG BH, CHOI EJ
  • 作者关键词:  
  • 出版物名称:   APPLIED PHYSICS LETTERS
  • ISSN:   0003-6951 EI 1077-3118
  • 通讯作者地址:   Univ Seoul
  • 被引频次:   4
  • DOI:   10.1063/1.4863416
  • 出版年:   2014

▎ 摘  要

We study the effect of self-assembled monolayer (SAM) organic molecule substrate on large scale single layer graphene using infrared transmission measurement on Graphene/SAM/SiO2/Si composite samples. From the Drude weight of the chemically inert CH3-SAM, the electron-donating NH2-SAM, and the SAM-less graphene, we determine the carrier density doped into graphene by the three sources-the SiO2 substrate, the gas-adsorption, and the functional group of the SAM's-separately. The SAM-treatment leads to the low carrier density N similar to 4 x 10(11) cm(-2) by blocking the dominant SiO2- driven doping. The carrier scattering increases by the SAM-treatment rather than decreases. However, the transport mobility is nevertheless improved due to the reduced carrier doping. (C) 2014 AIP Publishing LLC.