• 文献标题:   Mechanistic Insights into the Fluorescence Quenching of Rhodamine 6G by Graphene Oxide
  • 文献类型:   Article
  • 作  者:   CHEN L, ZHANG L, JIANG SL, ZHANG Q
  • 作者关键词:   graphene oxide, rhodamine 6g, fluorescence, carbonyl group, static quenching, sphere of action, groundstate complex
  • 出版物名称:   CHINESE JOURNAL OF CHEMICAL PHYSICS
  • ISSN:   1674-0068 EI 1003-7713
  • 通讯作者地址:   Univ Sci Technol China
  • 被引频次:   0
  • DOI:   10.1063/1674-0068/31/cjcp1710196
  • 出版年:   2018

▎ 摘  要

The fluorescence quenching of Rhodamine 6G (R6G) by graphene oxide (GO) was interrogated by R6G fluorescence measurements using a set of controlled GO samples with varied C/O ratios as the quencher. The carbonyl groups on the GO nanosheet turned to play a dominant role in quenching the R6G fluorescence. The quenching in the static regime can be described by the "sphere of action" model. The significant absorption of the R6G fluorescence by the ground-state complex formed between R6G and GO was identified to be responsible for the static quenching. This work offers helpful insights into the fluorescence quenching mechanisms in the R6G/GO system.