• 文献标题:   Graphene Nanosheets Modified Glassy Carbon Electrode as a Highly Sensitive and Selective Voltammetric Sensor for Rutin
  • 文献类型:   Article
  • 作  者:   DU HJ, YE JS, ZHANG JQ, HUANG XD, YU CZ
  • 作者关键词:   rutin, graphene nanosheet, electrocatalysi, sensor, stripping differential pulse voltammetry
  • 出版物名称:   ELECTROANALYSIS
  • ISSN:   1040-0397 EI 1521-4109
  • 通讯作者地址:   S China Univ Technol
  • 被引频次:   37
  • DOI:   10.1002/elan.201000110
  • 出版年:   2010

▎ 摘  要

Graphene nanosheets modified glassy carbon electrode (GNs/GCE) was fabricated as voltammetric sensor for rutin with good sensitivity, selectivity and reproducibility. The sensor exhibits an adsorption-controlled, reversible two-proton and two electron transfer reaction for the oxidation of rutin with a peak-to-peak separation (Delta E-p) of 26 mV as revealed by cyclic voltammetry. Moreover, the redox peak current increased about 14 times than that on bare glassy carbon electrode (GCE). The linear response of the sensor is from 1 x 10(-7) to 1 x 10(-5) M with a detection limit of 2.1 x 10(-8) M (S/N = 3). The method was successfully applied to determine rutin in tablets with satisfied recovery.