• 文献标题:   Ni nanoparticle supported reduced graphene oxide as a highly active and durable heterogeneous material for coupling reactions
  • 文献类型:   Article
  • 作  者:   RANA S, VARADWAJ GBB, JONNALAGADDA SB
  • 作者关键词:  
  • 出版物名称:   NANOSCALE ADVANCES
  • ISSN:   2516-0230
  • 通讯作者地址:   Univ KwaZulu Natal
  • 被引频次:   3
  • DOI:   10.1039/c8na00245b
  • 出版年:   2019

▎ 摘  要

We report the loading of highly air stable Ni(0) nanoparticles (average particle size 1/4 11 nm) on the surface of a reduced graphene oxide (RGO) material. The material was characterized using different techniques, including Raman spectroscopy, XRD, TEM, SEM, and HRTEM analysis. The Ni(0)@ RGO catalyst showed superb efficiency towards Kumada-Corriu C-C cross-coupling reactions, with 92% yield of 4methoxybiphenyl at 60 C. The recycled material can be reused up to the 5th cycle after regeneration by calcination, without loss of activity.