• 文献标题:   Stretchable all-solid-state supercapacitor with wavy shaped polyaniline/graphene electrode
  • 文献类型:   Article
  • 作  者:   XIE YZ, LIU Y, ZHAO YD, TSANG YH, LAU SP, HUANG HT, CHAI Y
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Hong Kong Polytech Univ
  • 被引频次:   166
  • DOI:   10.1039/c4ta00734d
  • 出版年:   2014

▎ 摘  要

A stretchable electronic device can retain its functionalities during high-level mechanical deformation, and stimulates the applications in the field of wearable and bio-implantable electronics. Efficient energy storage devices are an indispensable component in stretchable electronic systems. To integrate power supplies together with electronic devices that are mechanically flexible and stretchable, we demonstrate a new kind of stretchable all-solid-state supercapacitor, which consists of two slightly separated polyaniline/graphene electrodes in a wavy shape, with a phosphoric acid/polyvinyl alcohol gel as the solid-state electrolyte and separator. The as-fabricated wavy shaped supercapacitor was encapsulated in an elastomeric substrate which can be stretched to a large extent without mechanical degradation. The supercapacitor exhibited a maximum specific capacitance of 261 F g(-1). Electrochemical cycling testing with the supercapacitor showed 89% capacitance retention over 1000 charge-discharge cycles at a current density of 1 mA cm(-2). The bending and stretching tests showed that the supercapacitor maintained high mechanical strength and high capacitance simultaneously, even under a strain of 30%. This stretchable all-solid-state supercapacitor shows great potential as an energy storage device for stretchable electronic systems.