• 文献标题:   Highly Exfoliated Graphite Fluoride as a Precursor for Graphene Fluoride Dispersions and Films
  • 文献类型:   Article, Proceedings Paper
  • 作  者:   FEDOROV VE, GRAYFER ED, MAKOTCHENKO VG, NAZAROV AS, SHIN HJ, CHOI JY
  • 作者关键词:   graphite, fluoride, graphene, dispersion, film
  • 出版物名称:   CROATICA CHEMICA ACTA
  • ISSN:   0011-1643 EI 1334-417X
  • 通讯作者地址:   Russian Acad Sci
  • 被引频次:   10
  • DOI:   10.5562/cca1972
  • 出版年:   2012

▎ 摘  要

We synthesized highly exfoliated graphite fluoride of approximate composition C2F by treating highly exfoliated graphite with CIF3. The formed material was found to be dispersible in solvents giving 1 to 5 layered fluorinated graphene. Dispersions successfully formed in polar organic solvents capable of establishing hydrogen bonds. The highest stability is achieved in branched alcohols such as tert-butanol. The dispersions may be further processed into thin films by vacuum filtration technique. Also, composite multilayered films of graphene fluoride and graphene may be prepared. (doi: 10.5562/cca1972)