• 文献标题:   N, S Codoped Hierarchical Porous Graphene Nanosheets Derived from Petroleum Asphalt via in Situ Texturing Strategy for High-Performance Supercapacitors
  • 文献类型:   Article
  • 作  者:   YANG W, DENG BJ, HOU LQ, TIAN JB, TANG YS, WANG S, YANG F, LI YF
  • 作者关键词:  
  • 出版物名称:   INDUSTRIAL ENGINEERING CHEMISTRY RESEARCH
  • ISSN:   0888-5885
  • 通讯作者地址:   China Univ Petr
  • 被引频次:   12
  • DOI:   10.1021/acs.iecr.9b00222
  • 出版年:   2019

▎ 摘  要

A facile yet rational strategy is highly desired for the synthesis of high-value-added carbon materials from cheap petroleum asphalt. Here, we develop an in situ texturing strategy for the synthesis of nitrogen and sulfur codoped hierarchical porous graphene nanosheets (N,S-hPGNs) by using dual-functional graphitic carbon nitride templates. The synthetic strategy avoids using additional sulfur sources and a cumbersome acid washing process. The well-developed pores and abundant heteroatoms endow the N,S-hPGNs with a high capacity of 302 F g(-1) at 1 A g(-1) and an excellent cycling stability. Moreover, the as-fabricated supercapacitors display a high energy density of 10.42 Wh kg(-1) at the power density of 250 W kg(-1), outperforming other previous carbon materials from petroleum asphalt. This work not only demonstrates the great potential of N,S-hPGNs for supercapacitors, but also provides a new avenue for the high-value-added utilization of petroleum asphalt.