• 文献标题:   Surfactant-Exfoliated Highly Dispersive Pd-Supported Graphene Oxide Nanocomposite as a Catalyst for Aerobic Aqueous Oxidations of Alcohols
  • 文献类型:   Article
  • 作  者:   ROSTAMNIA S, DOUSTKHAH E, KARIMI Z, AMINI S, LUQUE R
  • 作者关键词:   alcohol, graphene, palladium, supported catalyst, surfactant
  • 出版物名称:   CHEMCATCHEM
  • ISSN:   1867-3880 EI 1867-3899
  • 通讯作者地址:   Univ Maragheh
  • 被引频次:   35
  • DOI:   10.1002/cctc.201500126
  • 出版年:   2015

▎ 摘  要

A pluronic P123 surfactant was employed in the exfoliation and stabilization of Pd-0-supported graphene oxide (Pd-NPs-GO; NPs=nanoparticles) nanosheets in aqueous solution during the oxidation of benzylic and aliphatic alcohols under aerobic conditions at 80 degrees C. Surfactants prevented the aggregation of Pd-NPs-GO sheets at 80 degrees C under aqueous conditions and Pd-NPs-GO/P123 adducts acted as a highly dispersive homogeneous-like catalyst. The catalytic performance of the nanocomposite material was remarkably improved, being highly stable and reusable in the aerobic oxidation of alcohols for at least nine runs.