• 文献标题:   Modified salicylaldehyde@ZIF-8/graphene oxide for enhancing epoxy coating corrosion protection property on AA2024-T3
  • 文献类型:   Article
  • 作  者:   XIONG LL, YU M, LI YQ, KONG XX, LI SM, LIU JH
  • 作者关键词:   compatibility, dispersion stability, interface interaction, corrosion protection property
  • 出版物名称:   PROGRESS IN ORGANIC COATINGS
  • ISSN:   0300-9440
  • 通讯作者地址:   Beihang Univ
  • 被引频次:   4
  • DOI:   10.1016/j.porgcoat.2020.105562
  • 出版年:   2020

▎ 摘  要

Salicylaldehyde@ZIF-8/graphene oxide (SZG) nanosheets were fabricated by anchoring salicylaldehyde@ZIF-8 nanoparticles on graphene oxide. SZG nanosheets were modified by amino silane 3-aminopropyltriethoxysilane (f-SZG) to improve the compatibility with epoxy coating. Sedimentation test showed the excellent dispersion stability of f-SZG in resin epoxy even after standing for 480 h. The cross-sectional microstructure of coatings implied the strong f-SZG/coating matrix interface by transforming the cleavage fracture to the ductile. Additionally, the stimuli-responsive release to H+ and Al3+ ions of f-SZG is maintained after the silanization. Compared with other samples, f-SZGO.5 epoxy coatings show the optimal long-term corrosion protection property with the lowest reduction rate of vertical bar Z vertical bar(0.01Hz) (13.6%) after 480 h immersion and the intact surface after 27d salt spray test due to the stronger interfaces of f-SZG/epoxy matrix and coating/substrate, the proper content (0.5 wt.%) and the enhanced cross-linked density of coating.