▎ 摘　　要

The efficiency and long-term stability of graphene (GR)/Si quantum dots-embedded SiO2 heterojunction solar cells are remarkably enhanced by employing bis(trifluoromethane sulfonyl)-amide (TFSA) as a dopant for GR. With increasing the doping concentration (n(D)) to 30 mM, the sheet resistance of the TFSA-doped GR transparent conductive electrode sharply decreases to similar to 191 Omega/sq with only 1% reduction in its transmittance at 550 nm. The DC conductivity/optical conductivity ratio saturates to similar to 62.5 at n D = 20 mM, resulting in maximum power conversion efficiency (PCE) of 16.61% and almost no loss of the PCE under 25 degrees C and 40% humidity atmosphere for 700 h. The solar cell also maintains similar to 94% (absolutely from 16.61 to 15.57%) of its initial PCE even under continuous light soaking of 1 Sun at 60 degrees C and 30% humidity for 1000 h. (C) 2018 Elsevier B.V. All rights reserved.