• 文献标题:   Nitrogen-doped graphene assists Fe2O3 in enhancing electrochemical performance
  • 文献类型:   Article
  • 作  者:   MENG XF, XU YL, SUN XF, XIONG LL, WANG QW
  • 作者关键词:   lithium ion battery, ndoped graphene, anode, porous property, prolonged cycle life
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Xi An Jiao Tong Univ
  • 被引频次:   18
  • DOI:   10.1016/j.jpowsour.2016.07.016
  • 出版年:   2016

▎ 摘  要

Fe2O3 anode suffers from drastic volume change during cycling and poor electronic conductivity, resulting in inferior electrochemical performance. To address these problems, the Fe2O3/nitrogen-doped graphene sheets hybridization strategy is proposed by a hydrothermal/annealing process. In this composite, Fe2O3 nanoparticles are tightly confined in graphene sheets matrix and the porous structure is obtained due to the crumpled and cross-like graphene framework, which can alleviate the volume expansion, maintain integrity of the electrode, and improve electrical conductivity and Li+ diffusion. As a result, benefiting from the synergistic effect of N-doped graphene sheets matrix and Fe2O3 nanoparticles, the composite exhibits a reversible capacity up to 952 mAh g(-1) at a current density of 100 mA g(-1) and excellent rate capability (348 mAh g(-1) at a current density 5000 mA g(-1)). (C) 2016 Elsevier B.V. All rights reserved.