• 文献标题:   Lithium storage performance of FeS@graphene anode materials prepared in a deep eutectic solvent
  • 文献类型:   Article
  • 作  者:   JU DC, CAO XC, LI H, ZHENG JC, CHEN CY, WANG ZT, QIU JY, ZHANG Y, LIU MM, ZHU QY
  • 作者关键词:   lithiumion batterie, deep eutectic solvent, ferrous sulfide, graphene, electrochemical performance
  • 出版物名称:   CERAMICS INTERNATIONAL
  • ISSN:   0272-8842 EI 1873-3956
  • 通讯作者地址:  
  • 被引频次:   6
  • DOI:   10.1016/j.ceramint.2022.01.228 EA APR 2022
  • 出版年:   2022

▎ 摘  要

FeS has received widespread attention due to advantages such as high capacity, low-budget, and friendly to the environment. But side reactions during the charging and discharging process result in volume expansion of FeS, which limits its application and further development. In this work, FeS@graphene composites were prepared by a single step pyrolytic sulfidation method using PEG as the carbon source, FeCl3 center dot 6H(2)O as the iron source, metal chloride and organic alcohol as a deep eutectic solvent. The prepared composites which were characterized by SEM and TEM exhibited a strong bond between FeS and graphene, graphene had a lamellar structure, and FeS nanoparticles formed a homogeneous dispersion. Among the prepared composite material electrodes, the FeS/G550 electrode displayed the best electrochemical properties with a high specific capacitance (initial discharge capacity: 1200 mAhg(-1); current density: 0.1 A g(-1)), excellent rate capability (discharge specific capacitance of 443 mAh.g(-1) at the current density of 5 A g(-1)), and good cyclic stability (capacity retention rate: 91%).